The rising star and then-boyfriend Brad Pitt sported matching blonde locks at The Devil's Own premiere in NYC in 1997.

In 1999, she nabbed an Oscar for Best Leading Actress wearing Ralph Lauren's taffeta dress for her breakthrough role in Shakespeare In Love.

he following year, she attended the awards show in a club-wear meets yoga ensemble.

The star buttoned up pal Stella McCartney's chic tailored blazer with a glitzy bohemian skirt at the 2001 VH1/Vogue Fashion Awards in 2001. Her other fave fashion designers? Alexander McQueen, Carolina Herrera, and Junya Watanabe.

Critics slammed Paltrow for her fashion and beauty faux pas at the Academy Awards in 2002: a see-through dress paired with severe-looking cornrows.

The pregnant star showed off her newfound curves in a two-toned biased cut Stella McCartney dress in 2004.

Paltrow looked lovely in nude colored strapless dress at the Vanity Fair Oscar Party in 2005.

The actress picked a Zac Posen dress and straightened her long locks at the 2007 Academy Awards.

The star debuted a shorter 'do and rocked a slim blazer over Alexander McQueen's strapless dress at an event in London March 18.

She took her hemline to new heights at the Iron Man premiere in London April 24